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101.
Tachikawa H Yabushita A Kawasaki M 《Physical chemistry chemical physics : PCCP》2011,13(46):20745-20749
A direct ab initio molecular dynamics method has been applied to a water monomer and water clusters (H(2)O)(n) (n = 1-3) to elucidate the effects of zero-point energy (ZPE) vibration on the absorption spectra of water clusters. Static ab initio calculations without ZPE showed that the first electronic transitions of (H(2)O)(n), (1)B(1)←(1)A(1), are blue-shifted as a function of cluster size (n): 7.38 eV (n = 1), 7.58 eV (n = 2) and 8.01 eV (n = 3). The inclusion of the ZPE vibration strongly affects the excitation energies of a water dimer, and a long red-tail appears in the range of 6.42-6.90 eV due to the structural flexibility of a water dimer. The ultraviolet photodissociation of water clusters and water ice surfaces is relevant to these results. 相似文献
102.
A. Sagisaka A.S. Pirozhkov H. Daido A. Fukumi Z. Li K. Ogura A. Yogo Y. Oishi T. Nayuki T. Fujii K. Nemoto S. Orimo M. Nishiuchi Y. Hayashi M. Mori M. Kado S. Nakamura A. Noda I.W. Choi J.H. Sung D.-K. Ko J. Lee 《Applied physics. B, Lasers and optics》2006,84(3):415-419
A two-color interferometer for preformed plasma characterization is developed. We observe the electron density distribution of preformed plasmas on a 5 μm-thick copper target irradiated with a high-intensity Ti:sapphire laser. The two-color interferometer extended the observable electron density region using a fundamental (800 nm) probe beam to cover the lower density region and a second harmonic (400 nm) probe beam to cover the higher density region, simultaneously. This characterization of the electron density distribution of preformed plasmas with femtosecond time resolution significantly contributes to the understanding of high-intensity laser–thin-foil interactions during high-energy electron, ion, and X-ray generation. PACS 52.38.-r; 52.50.Jm; 52.70.-m 相似文献
103.
In order to investigate thermal behaviors of the hydrogen species, H+ ion and H atom, adsorbed on the surface of planar graphite, the direct molecular orbital dynamics (MO) calculations at AM1 level are applied to the hydrogen terminated planar cluster models included by the species, C54H18·H+ and C54H18·H, respectively. This is the first trial to describe the thermal behaviors of these species in terms of MO dynamics. Both hydrogen species form the covalent bonds with the surface carbon atoms through the sp3 hybrid orbitals which inhibit their dissociation at high temperature up to 2000 K. It was found that the reduction of band gap is introduced by the adsorption of H+ ion. 相似文献
104.
Ge Tian Qiong Wu Suqin Sun Isao Noda Guo‐Qiang Chen 《Journal of Polymer Science.Polymer Physics》2002,40(7):649-656
Generalized two‐dimensional (2D) Fourier transform infrared correlation spectroscopy was used to investigate the effect of the comonomer compositions on the crystallization behavior of two types of biosynthesized random copolymers, poly(hydroxybutyrate‐co‐hydroxyhexanoate) and poly(hydroxybutyrate‐co‐hydroxyvalerate). The carbonyl absorption band around 1730 cm?1 was sensitive to the degree of crystallinity. 2D correlation analysis demonstrated that the 3‐hydroxyhexanoate units preferred to remain in the amorphous phase of the semicrystalline poly(hydroxybutyrate‐co‐hydroxyhexanoate) copolymer, resulting in decreases in the degree of crystallinity and the rate of the crystallization process. The poly(hydroxybutyrate‐co‐hydroxyvalerate) copolymer maintained a high degree of crystallinity when the 3‐hydroxyvalerate fraction was increased from 0 to 25 mol % because of isodimorphism. The crystalline and amorphous absorption bands for the carbonyl bond for this copolymer, therefore, changed simultaneously. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 649–656, 2002; DOI 10.1002/polb.10126 相似文献
105.
Takashi Noda 《Numerische Mathematik》1971,17(5):382-386
Summary We prove the convergence of Wielandt's method in the computation of the maximal eigenvalue and eigenvector of a non-negative irreducible matrix. 相似文献
106.
Neutron scattering measurements have been made of phonons in a Fe65Ni35 crystal at several temperatures. Marked softening of the [110] acoustic shear modes and a dip in the dispersion relation are found at low temperatures. Above the magnetic ordering temperature Tc, the frequency shift is removed completely, which suggests phonon perturbation by magnetoelastic coupling. 相似文献
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